A 22 year old fresh out of college student with a $68,000 salary? GET HIM HERE!
Max the 401k AND max out a Roth or IRA after that, beginning with the FIRST paycheck. He was probably just living the past 4 or 5 years on about $10,000- $15,000 per year, not counting tuition.
He now has the opportunity to live on almost TRIPLE that income, AND max a 401k, AND max a Roth or IRA. He will never again have such a jump in income as a percentage of his current cost of living.
I would max the 401k first due to the high maximum ($19,000 for 2019). This is a "use it or lose it" bin that should only be left unfilled if absolutely necessary. Get a side hustle if you need to, but max that 401k!
As far as Roth or IRA up to the limit($6,000 for 2019), it would depend on whether his future self will have more or less income and whether his tax rate changes(not at all predictable). A FIRE person should go with a 401k and convert to Roth after his working life. Life long worker most likely should go Roth.
The bigger answer here is MAX the 401k AND max either a Roth or IRA. The high fees over a lifetime would be HUGE, but every job change allows us to roll over into low cost options. A few years of high fees is worth that. And he should be pestering HR to get more reasonable choices if the fees are indeed high.
If he does not max them both(he should), use the list created by
@runningthroughFIRE.
Keep us posted.