What's interesting to me is for my power company (in GA), I'm still better off with the standard rate.
I use around 200 kWh a month year round (I live in a basement apartment which lets me leave my A/C off a lot. But then I turn on my dehumidifier sometimes).
In both winter and summer, under the standard rate, the cost of the first 650 kWh is the same, 5.6582 cents/kWh (it's much higher for energy usage over 650kWh in the summer).
Under the "Night and Weekend" rate, the peak time is defined as 2pm to 7pm on weekdays in June through September. The off peak rate is 4.643 cents/kWh, and the on peak rate is 20.3217 cent/kWh.
So my maximum benefit (if I only ever used electricity during off peak times) is $2.03 a month. Eight months of the year is always off peak, so that's $16.24 in guaranteed savings.
But what of the summer months?
I'd have to use no more than 39kWh a month in June thorugh Sept during peak hours for all the savings from the rest of the year to overcome the extra cost of peak hour electricity usage. That to me seems like a lot of risk for so little gain.
If I were to decide to switch to the Night and Weekend rate, I have to stay on that rate for an entire year (makes sense).
It's definitely worth doing the math, as I'm sure you've done.