Good working order except for seeming to have issues getting the chain to get onto the largest gear near the pedals.
I presume you mean you're having trouble shifting the front derailer onto the largest chainring? Could be one of two things:
1) High limit screw too tight. This is the easy one. On the front derailer, there should be two screws labelled H and L. Try to shift onto the largest chainring--push the shift lever as far as it can go. With a flashlight you should be able to see the far end of the H screw inside the mechanism. If it's touching something, back it out a little--this should let the derailer move out more and shift onto the large chainring. It should be adjusted to allow shifting, but not throw the chain off the outside.
2) If the high limit isn't touching, it's not the issue. You'll need to increase the tension on the front derailer cable. The cable attaches to the derailer at a hex screw, loosen that a little and pull more cable. (A third hand, literal or figurative, helps.) Make sure to tighten it back down well!
AASHTA:
http://www.sheldonbrown.com/derailer-adjustment.htmlAlso, I hope you're working on the brake system, not the break system ;)