Call her up, tell her you would like to buy her third out, and get an appraisal. If all parties agree on the appraised value, write the check.
If you don't do this, the aunt could force a partition, which would mean a court-ordered sale.
ETA: If he has a "life estate" in the property, which he may have, given he is required to pay the property taxes, the property is encumbered and the value of the aunt's interest is less than a third of fair market value. She would not be able to get full value even if she could force a partition in that situation.