We used this on our south and west facing windows.
https://www.homedepot.ca/product/gila-light-heat-control-window-film-3-feet-x-15-feet/1000686185 This one is almost invisible when installed, and has stood up well for over 10 years now. We're moving in a couple of weeks, and I intend to reorder and use it at the new house too. (older windows without the anti-glare, etc. gas between the double panes).
There are thicker ones, and we did try the titanium one on the patio door. Did not like that one! Harder to install, and darker tint means you don't see through it as well when you're inside.
There are two layers of film in the roll - one is the mylar backing, and one the actual film. (for the reviews that said it fell off the window, um yes, they didn't take the backing off!). Make sure which is which, and be very careful to not get dust, hair, etc. on the back of the actual film when you separate the layers. Do all the cutting/fitting with the backing attached, and put it up much like mac tac or vinyl peel and stick shelf liner. Spray the window (be generous with the water), peel back a small area at the top, get that set, and then work your way down the window. Keep the area to be done well wetted.
Do not follow their instructions though re: solution, etc.! You don't need anything but a spray bottle with just water in it - no detergent, etc. And don't use the squeegee provided. A plastic credit card works much better, (work at about a 45 degree angle to the film) and allows you to work smaller areas to get the air bubbles out. There will be a few stubborn small air/water bubbles the first day, but as the film dries most will disappear. If not, pierce with a small pin and rub with a towel or microfiber cloth. It will make a mess on the floor - put down towels to catch the water you squeegee out. If you ever want to remove it, just peel it off. Leaves no marks, etc.