Between your expenses and 401k contribution I'm figuring that you conservatively still have about 25k unspoken for. I came to this by estimating 1500 per month for expenses, 6k for your 401k contribution, and taxes.
So if you have 25k left over, I would set the goal of completely paying off your student loan and maxing out your IRA/Roth. Once the student loan is gone, increase your 401k contributions as you work on paying off the car.
Ideally you want to get to the point where you're maxing out your 401k (in your case that's 30% of your salary), maxing your ROTH/TradIRA, and THEN doing after tax investing. What you decide on largely depends on your goals. If you plan to stop working/work less before age 59.5 then doing some after tax investing will be necessary although mathematically it's not the best way to go.
VTI is fine investment for your IRA.
Hope this helps.