Author Topic: Phase change materials for home comfort.  (Read 4857 times)

MoonShadow

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Phase change materials for home comfort.
« on: July 20, 2015, 10:36:21 PM »
MMM talks about sucking it up and doing without central air conditioning to save money, but there simply are places in the US that become difficult to live in without AC for a couple weeks each summer.  I wanted to share a couple of ideas I had about dealing with that particular problem.

I live in Kentucky, which tends to be rather humid for most of the summer months, but only during the 'dog days' of summer is air conditioning truly required; so I look around my house, and see all of the modern marvels that make our lives easier (i.e. computers, dishwashers, refrigerators, ovens, washers & dryers (tried the clothesline thing, doesn't work reliablely in Kentucky's climate, if it's not too humid for the clothes to dry before they smell like mildew, it's already raining) ) and I, of course, can't help but notice that all of them take energy to function, and therefore put off heat.  This is fine for two-thirds of the year, since they contribute to the heating demand of the home, but that last third of the year, we are fighting against the natural flow of energy.  And that is a costly fight.

While at my workplace, a factory, the entire factory is heated in winter, as the machines contribute to the heat demand.  However, during the summer season, only certain areas are are conditioned; functioning as respites from the heat & humidity on the worst days.  These areas include restrooms, offices and meeting rooms; but not the factory floor where the vast majority of the machines reside.  I propose taking a small inner room, one with no exterior walls, and making a getaway room during the worst heat of the summer day.  This is similar to what children would do during the 'dog days' by hiding inside the family root cellar for a couple hours playing games like jacks or marbles.  A modern walk-in closet fits the bill nicely.

So, then, how do we keep the room cool?  Well, I have thought of two potentially low cost ways of doing so.  The first, and the title of this post, is to use a phase change material in safe containers stored in the getaway room.  The ideal material for this purpose is heptadecane, which is basicly just a purified form of wax, similar to petroleum jelly, with a melting point about 72 degrees F (that's about 22 degrees C for our metric friends).  I've found this purified oil/wax can be bought in 5 gallon buckets from a few places around the web.  (this is just one, not a recommendation; http://www.jbwax.com/Products.html )

We could place the 5 gallon buckets into the getaway room as they are, and use them as the base for a small table or some such, or transfer the wax into cleaned pickle jars, peanut butter jars, etc.  As long as they were well cleaned, and well marked (so no one could mistake it for something actually edible, if we were to use this getaway room as an actual pantry also); the additional surface area of the containers might improve performance.  The room cold be sealed & insulated, or not, but there shouldn't be any power using machines inside the room, nor should the lighting be anything other than the most energy efficient available, presently LEDs.  With a decent LED reading light & comfortable chair, this room could be a refuge from the heat of the world.

But the above method pretty much assumes that the house can cool off below 70 F overnight, and give the wax a chance to divest it's accumulated heat and solidify.  In some areas, that's not realistic.  For those areas, I have a moderately cheap solution as well.  Somewhere nearby, but not in the getaway room, a small deep freezer should be sighted.  It can be a beat up one from craigslist, or even an older & less efficient one if you can get it cheap enough, because we won't be keeping food in it, and we won't be running it all year.

We will be placing plastic jugs of water (old juice or milk jugs, but the clear juice bottles are more likely to survive several freezings than milk jugs are).  A week or so before the actual 'dog days' start (yes, we all know roughly when that happens in our area; in my area it's no sooner than mid-July an runs through August; but isn't continuous.  Other areas may have a different pattern.) we stock the deep freezer with water bottles, and let it run unmolested.  When the real heat hits and we need to escape, we turn on an aquarium air pump that is inside the deep freezer and has tubing running into our room, ending with air stone diffusers above our reading chair (cold air falls) and we prop the top of the deep freezer open slightly with a small object (just the tubing itself might be enough) so that air has a chance to enter into the deep freezer as we pump it out with the aquarium pump.  We can unplug the deep freezer, or not; it won't matter in the couple hours we are reading a good book, or listening to our favorite podcasts in the dark, or just napping in a recliner.  Once the peak heat of the day is past, and we can't really read, listen or nap any longer; we just turn off the aquarium pump and close the freezer lid.  It will recover by the next day.  Once September starts, we unplug the deep freezer for the year, remove the ice bottles (use them in your cooler? water the houseplants with meltwater?) and prop open the lid to allow it to dry out till next summer.

Any thoughts or critiques?

deborah

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Re: Phase change materials for home comfort.
« Reply #1 on: July 21, 2015, 12:34:52 AM »
Dig out a cave - underground stays the same temperature year round.

MoonShadow

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Re: Phase change materials for home comfort.
« Reply #2 on: July 21, 2015, 01:02:23 AM »
Dig out a cave - underground stays the same temperature year round.

Sure, around here that would be 55 degrees, but you have to go about 20 feet down first.  Sounds like a lot of work for three weeks per year.  And it's damp. 

Arktinkerer

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Re: Phase change materials for home comfort.
« Reply #3 on: July 21, 2015, 07:54:24 AM »
is to use a phase change material in safe containers stored in the getaway room.  The ideal material for this purpose is heptadecane, which is basicly just a purified form of wax, similar to petroleum jelly, with a melting point about 72 degrees F (that's about 22 degrees C for our metric friends).  I've found this purified oil/wax can be bought in 5 gallon buckets from a few places around the web.  (this is just one, not a recommendation; http://www.jbwax.com/Products.html )


I did a paper on this while in high school for a science competition back in the 80's.  Created a computer model of how to use two compounds to adjust the melting point of a material for passive solar systems.  Melting points generally go down as you add a second chemical to a mixture.  There are a number of materials that can be adjusted to melt at comfortable room temperatures.  Waxes are a good one but like many materials that have a low melting point they are usually flammable! 

Later, I learned that a number of places were using different varieties of salts in solution.  The energy storage (heat of fusion) was not as high but the material is safer.  The transition temperature was actually a wider range--as the temperature changed the salt goes into or out of solution.  I think the material was also much cheaper so you get more energy storage for your $ even if it takes up marginally more space.


waffle

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Re: Phase change materials for home comfort.
« Reply #4 on: July 21, 2015, 08:15:30 AM »
I'm lucky enough to have a basement that stays pretty cool. We don't actually hang out in the basement (its unfinished still), but when it gets uncomfortably hot upstairs we crack a window in the basement and turn on the attic fan to draw the cool basement air upstairs.

The wax oil idea or anything with significant thermal mass has some merit, but I think will only get you so far. The human body puts off a significant amount of heat and if your getaway room is somewhere small like a closet then I think your body may heat up the confined space at a quicker rate than the wax will absorb the heat. That's just my initial gut feeling on it without any actual data. It would of course depend on how much wax you have in the room. I'm sure there is a equilibrium point, but I don't know how much wax it would take to keep x amount of cubic feet x amount cooler than the surrounding rooms.

The freezer idea would certainly work, but (again just my initial gut reaction to it without any data) it seems like it would be cheaper and save a lot of space to just have a small window ac unit that you run for an hour or two a day rather than a chest freezer that has to run all day.

MoonShadow

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Re: Phase change materials for home comfort.
« Reply #5 on: July 21, 2015, 08:32:47 AM »
is to use a phase change material in safe containers stored in the getaway room.  The ideal material for this purpose is heptadecane, which is basicly just a purified form of wax, similar to petroleum jelly, with a melting point about 72 degrees F (that's about 22 degrees C for our metric friends).  I've found this purified oil/wax can be bought in 5 gallon buckets from a few places around the web.  (this is just one, not a recommendation; http://www.jbwax.com/Products.html )


I did a paper on this while in high school for a science competition back in the 80's.  Created a computer model of how to use two compounds to adjust the melting point of a material for passive solar systems.  Melting points generally go down as you add a second chemical to a mixture.  There are a number of materials that can be adjusted to melt at comfortable room temperatures.  Waxes are a good one but like many materials that have a low melting point they are usually flammable! 

Later, I learned that a number of places were using different varieties of salts in solution.  The energy storage (heat of fusion) was not as high but the material is safer.  The transition temperature was actually a wider range--as the temperature changed the salt goes into or out of solution.  I think the material was also much cheaper so you get more energy storage for your $ even if it takes up marginally more space.

Yes, but aren't those salts toxic?  Would you have a recommendation of such a salt with a target temp of 68 to 72 degrees?

CowboyAndIndian

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Re: Phase change materials for home comfort.
« Reply #6 on: July 21, 2015, 08:37:46 AM »
Sure, around here that would be 55 degrees, but you have to go about 20 feet down first.   

No, you need to go 5  feet down.

I basically live in my finished basement on those days. Stays around 70 degrees F.

zolotiyeruki

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Re: Phase change materials for home comfort.
« Reply #7 on: July 21, 2015, 01:06:58 PM »
Southern Yellow Pine is what you're after.  The resin in it has a transition temperature of about 72 degrees.  Non-toxic, non-volatile, and it takes a lot more effort to catch on fire. :)  And since it's wood, it won't look out of place inside your home!

MoonShadow

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Re: Phase change materials for home comfort.
« Reply #8 on: July 21, 2015, 01:26:27 PM »
Southern Yellow Pine is what you're after.  The resin in it has a transition temperature of about 72 degrees.  Non-toxic, non-volatile, and it takes a lot more effort to catch on fire. :)  And since it's wood, it won't look out of place inside your home!

I'd say that wax inside a sealed jar is much less likely to catch fire than yellow pine, since that's exactly what I use as a firestarter in my woodstove.  Either way, such risk is remote.  Neither material is known for spontaneous ignition.

beltim

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Re: Phase change materials for home comfort.
« Reply #9 on: July 21, 2015, 01:34:08 PM »
I have to admit I was skeptical that this would work but then I did a little back of the envelope calculations:

The heat of fusion of heptadecane is 152 kJ/kg according to http://www.jbwax.com/Products.html

So a total of, say, 50 kg (about 17 gallons) of heptadecane would have a total heat capacity of 7600 kJ.  The specific heat of air is about 1 J / g °C, so a 5m x 3m x 2.5m room would have 37.5 cubic meters of air, or about 45 kg of air.  That's 45 kJ / °C then that you'd have to worry about.  7600 / 45 = about 170 degrees that you have to play with.  But there is, of course, ventilation - a passive house standard has 0.6 air changes per hour, so a well insulated room like this would probably be about 1 change per hour.  Over the course of, say, a 10 hour day, you could prevent an increase of 17 °C.  So you could keep a room at 22 °C instead of 39 °C or 102 °F.

Of course, that's just the thermodynamics, not the kinetics.  And, as MoonShadow points out in the original post, it is utterly dependent on the room cooling off every night - and I've usually found that the only times you'd need something like this are the exact times that it doesn't sufficiently cool off at night.  But, I thought the calculations showed the thermodynamic feasibility in a pretty neat way, so I figured I'd post them in case anyone else was interested.

TrMama

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Re: Phase change materials for home comfort.
« Reply #10 on: July 21, 2015, 02:49:41 PM »
Or, just get one of those little window A/C units and put it in your bedroom window. We have a couple for the worst of the summer heat and they don't affect the electric bill at all. Plus, no worry of my kids getting into chemicals.

MoonShadow

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Re: Phase change materials for home comfort.
« Reply #11 on: July 21, 2015, 06:43:34 PM »
Or, just get one of those little window A/C units and put it in your bedroom window. We have a couple for the worst of the summer heat and they don't affect the electric bill at all. Plus, no worry of my kids getting into chemicals.

Yeah, I suppose that would work well also.

EDIT: heptadecane is just refined candle oil, and is about as toxic as a candle.  Not something that should be eaten, but not exactly poison either.  The salts, however, will hurt if consumed.
« Last Edit: July 21, 2015, 06:45:52 PM by MoonShadow »

Emg03063

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Re: Phase change materials for home comfort.
« Reply #12 on: July 31, 2015, 05:41:22 AM »
Your limiting factor is not going to be the heat capacity of the material, but the rate of transfer in and out of it.  To be effective, you need to have significant surface area of the PCM thermally exposed relative to the volume of the room.  There's a commercial product called biomat designed to do this by mounting behind your drywall (you could mount it to the inside of the room as well, I suppose, if you don't care about aesthetics), but the last time I priced them (it's been a couple of years), radiant barrier and plain old ordinary insulation had much better ROI.  I have used water in gallon jugs piled all around my house to buffer temperature swings, with somewhat reasonable success (I didn't buy the bottles--I had a crazy ex roommate who didn't trust filtered tap water, so I just saved the bottles he would buy).

http://www.phasechange.com/index.php/en/

 

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