I'm new to this, too.
Here's my plan:
Start with a low temp, 40-50 degrees C. In the autumn when you just need a little bit of heat, that will do. A day will come when it's heating all day at that low temp but the house is still colder than it should be, that's when I'm planning on raising the outflow temp. Rinse, repeat. Note the outside temperature at each change, and do the same thing in reverse order in the spring.
Or just install an OTS and rely on it.
Decisions, decisions...
There are 2 'power' ratings on my boiler, at 80 degree C outflow temp it puts out a certain amount of heat, at 50 degrees the number is 10 percent higher, same amount of fuel used. That's the efficiency gain of condensing.