I've heard of something like this, I think it would almost certainly work to your advantage, since electricity providers will probably build in a margin on a flat rate to ensure they'll make money even when demand is high, whereas with the real time rates they'll be able to keep rates closer to actual. The ones I've heard of aren't real time pricing, they're scheduled- so say, electricity from 12PM-5AM will be priced at a lower rate since demand is typically lower around then. This takes it one step further.
I don't imagine that you'd actually be checking the real-time rates all the time, but instead figuring out demand patterns generally so you can schedule certain appliances and activities (dishwasher, washing machine, dryer, A/C or heater) to run when rates are lower.