While I can't put specific numbers to it, my sense would be that the xa for $2k (half) the price and ~65k fewer miles. Yes, the priuses (Prii?) can often run well past 300k properly cared for, but on the same note the xa should go well past 200k with similar care. Both cars have CV joins, ICE, etc. which will need periodic maintenance and replacement -- the fewer miles on the xa means it should have fewer of these repairs sooner.
Your daily round trip of 40 miles = ~10,000/year, add errands and driving vacations and you're probably at the national average of ~12k-15. Assuming the higher, the xa should last you another 5+ years. Ergo, depreciation (if we assume its sold for scrap) would be less than $1/day.The prius will save you $200 in fuel, but over that same time period will likely cost a bit more in depreciation. DOubly so if it means holding on to an extra $2k in loans and loan payments during that timeframe.
Final question - do you have to drive on a lot of unpaved roads for this job? When I was fresh out of college I drove a jetta and had a job working at two remote field stations. I loved how the vw's fuel economy but it was an example of being penny-wise and pound-foolish; the damage I did on that car (mostly suspension issues) negated any fuel savings I made.