Your A/C will run more the higher the temperature difference is. Here's an example:
Nighttime
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Inside: 75, Outside 80, Difference 5 degrees (not much work)
Daytime
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Inside: 75, Outside 90, Difference 15 degrees (plus direct solar gain/greenhouse effect = much more work)
For me, I also have a time of use plan where I pay more for usage from 1pm to 8pm on weekdays, but less at all other times. In general, I set my thermostat to 78 overnight, 80 at non-peak times, and 83 from 1pm-8pm Monday-Friday. That has helped me to reduce the total power used as well as optimize the cost by aligning the temperature changes with the electric rates.
It sounds like this is basically what you are already doing, so I would say you can keep doing what you're doing.