Some cars have an "overflow" tank with a hose going from the radiator to the bottom of the tank. If the heat / pressure gets too high, some cooling fluid will flow into the overflow tank,- conversely when the system cools after the car is shut off, a vacuum can be created, and if the overflow tank is empty, or the hose is not set at the bottom, it can pull air into the system.
The temperatures in the cooling system are kept lower by having a pressurized system. On old cars the pressure was "set " by a relief valve in the radiator cap. Have you tried replacing the cap ? Also there is a additive called "water wetter" it's red and comes in an approx 12oz bottle, it helps transfer heat out of/ into the coolant . You can try adding this, costs about $10.
Is your radiator cooled by a fan driven by a belt and pulley [mechanical], or by an electric fan{s}. Sometimes the electric sending unit that senses the temperature and tells the electric fan to start goes bad, resulting in the fan not starting and/ or starting at a higher temp than factory setpoint.