The ability to open a solo 401(k) after December 31st at all is a new thing within the last few years and people who have done so is kind of an edge case since it only applies the first year, so I expect the calculator author just decided it wasn't worth customizing and option for that.
Catch up contributions are employee contributions, so no, you wouldn't be able to make this this year either since you can't have declared them in time.
The highest value Step 4 can be is 20%, so just use that. It's kind of silly, but it's just that the max profit share percentage for a solo 401(k) is 25%, but you can't make a profit share contribution on the profit share contribution. The table below the worksheet is just solving for the equation X/(1+X) where X is the desired contribution percentage. Assuming you want to max the contribution just use 20% and you don't need to worry about that though.
Make sure you exclude $10,200 of your unemployment income per the stimulus bill passed Thursday if your total AGI is under $150k. It might take some time for tax software to catch up with this.