I make my own soap (a hobby that probably doesn't save much money, but I like knowing what's in my hygiene products, and it's fun.) When I cut a block of fresh soap into bars, there are always scraps and shavings that aren't really good for washing with.
So I save them, let them dry out, then throw them in a crock pot with some water. Once all the soap dissolves, I add a cup each of borax and washing soda, pour it into old detergent containers, and then fill the rest up with water.
Now I have 9 full containers of laundry detergent that I made for next to nothing. It's not exactly a get-rich-quick scheme, but it makes me happy. :)