In scope and money, I'm going with FIFA. Both FIFA and IOC are global, so everybody knows about them. Both FIFA and the NCAA rake in hordes of money. Since FIFA hits both those corruption targets so well, my vote is on them.
Key point, NCAA uses an unpaid labor force with rules and regulations in place to keep it that way for some absurd concept of amateurism.
Also, given that some cities outright campaign not to host the Olympics (check out Boston's anti-Olympic campaign), I think the IOC is tame in that department. (Whereas FIFA officials take bribes from countries to host the Men's World Cup.)
Even so, FIFA's 4 year revenue cycle is roughly $6.4 billion, the IOC's 4 year revenue is a surprising $5.7 billion, and the NCAA reports a paltry annual $1 billion.