Thanks! I've also read about someone recommending to have a spray bottle of water/dish detergent and sort of spraying the bead and area before or while smoothing it out - this to kill bacteria and prevent mold/mildew and growth. Would you recommend doing this? Anything else to take into consideration whilst prepping for or applying the silicone?
BTW: would acetone or Googone work for removing any excess silicone that didn't come off from scraping it off?
Just did this exact DIY project, replacing silicone caulk behind sink between stone counters and backsplash. Get all the old caulk out, a painting multi tool is great for this, then finish up with a razor blade.
Critical to cut the tube to the right size - a too big opening will make a huge mess. start with a small opening you can always cut larger as needed.
Cut open tube at around 45 degree angle, then a 15 degree cut in the opposite direction across the cut you just made. This will allow you to hold the tube at 90 degree angle to the work area, and reduce smear off the sides as you push the caulk down the line. Face the larger cut towards the direction you are pushing and the smaller cut side trailing, will leave a really close-fit bead of caulk.
If you wind up with the wrong opening size it's worth the $5 to cut a new tube vs making a huge mess. Silicone is a pain to clean up and making sure just the right amount goes down is your best bet.
The spray bottle of soapy water + bare finger works great. I sprayed my finger and then ran it along the bead. If you are doing a particularly long run spray multiple fingers on one hand and switch fingers as they start to dry out. Silicone sets pretty quickly but you can still do 12"-24" sections and have a seamless look.
A square or two of TP to immediately clean of fingers is a must.
While silicone is notoriously challenging, these tips made it possible to do a shower surround, bath vanity, and kitchen counter/blacksplash joint the other day with minimal mess/cleanup and a very professional looking result. Good luck!