Not an easy DIY project.
Don't use your existing water heater.
I'd probably get a bid from a plumbing/heating/HVAC company, though admittedly this could be difficult since they want to control the entire installation so they don't charge you $10,000 to install a boiler/on demand heater and hook it up to a system with major issues and have an unhappy customer they can't please.
If the PEX is buried in cement or mortar, then it's really tough to inspect it.
Maybe there's a portable boiler/pump they can bring to test it, I don't know.
Good luck!