Trace the pipe going into the boiler, there should be a valve (quite possibly a round red wheel) that you can turn. If not, keep tracing the pipes running in to the boiler back until you get to a shut-off point: a gate valve, a ballcock over a water tank, the stopcock under the sink, etc. The closer to the boiler, the more the rest of the system will keep working, so you will have loos to flush and water at the kitchen sink.
Make sure the electric power to the boiler is switched off, so it doesn't empty out and blow up!