Just an update here:
DIY Repair: I have replaced all the return pipes in the basement with their original appropriate material, black iron. After taking meticulous measurements, diagramming, and labeling, I purchased the pipe from Lowes and they cut and thread for no charge. The fittings I purchased from plumbingsupply online. Roughly a $400 repair. Working with the pipe was tough, but after gathering all the materials, the job was completed in one day.
Results: I used to hear the low-water auto-fill valve replenish my boilers water supply 1x-3x per day. So far this winter, I've only heard it fill 3x total! This means more 70+ degree steam condinsate returning to the boiler, as opposed to 50 degree supply water. This should equal less gas burned to create the steam.
DIY Install: $270 Craigslist pellet insert and $500 25' chimney liner kit. Lining the chimney was a very tough and dangerous job, but it was completed without injury.
Results: I'm very proud of the job, but I wish this insert would throw out as much heat as other stoves I've seen. It's steel, as opposed to cast iron, which means it heats quickly, but fails to retain the heat after the unit is shut off. Also, being that it is pellet, it will not function in the event of power loss. The fact that I only paid $270 makes me feel good, because I doubt this investment would ever pay for itself if I paid retail $.
Forgot to add this-
DIY Install: Reinstalled two steam radiators that had been sitting in my basement, disconnected and collecting dust. My single-pipe steam system is piped to utilize 8 radiators. When I moved in, only 6 were connected, with a 7th stored in the basement. We renovated the kitchen, disconnecting a radiator to make room for kitchen cabinets. The system was down to 5 of 8. We hoisted the old kitchen radiator to the new baby's bedroom upstairs, to a capped off pipe. The radiator from the basement was connected to a capped of pipe in the dining room.
Results: I believe this made the whole system more balanced, and the house seems to be heated more evenly. I don't believe that the boiler has to create a significant amount more steam to fill the additional radiators, but the utility bill will tell the tale.